Crystal structure of chlorido (2-(4-ethylphenyl)pyrimidine-k2C,N)(triphenylphosphane-kP) palladium(II), C30H26ClN2PPd

Experimental details A suitable crystal was selected and measured on an Xcalibur, Eos, Gemini diffractometer

Hui Liu; Xin-Hua Lou

2020

Scholarcy highlights

  • Experimental details A suitable crystal was selected and measured on an Xcalibur, Eos, Gemini diffractometer
  • A wide variety of phosphines adducts of palladacycles have been successfully used in coupling reactions
  • There have been a few reports which demonstrated that pyrimidine can act as a directing group for cyclopalladation
  • The title complex has a trans-geometry in the solid state and the Pd atom is in a slightly distorted square-planar environment provided by a chloride, a P atom, and the C atom and the N atom of the 2-(4-ethylphenyl)pyrimidine ligand
  • In the crystal there exist C—H· · · N and C—H· · · Cl hydrogen bonds , which are attributed to construct the 1D lamellar structure

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