Syntheses and Structural Characterization of a LAl(N3)N[μ-Si(N3)(tBu)]2NAl(N3)L and a Monomeric Aluminum Hydride Amide LAlH(NHAr) (L = HC[(CMe)(NAr)]2, Ar = 2,6-iPr2C6H3)

Reactions between the aluminum(I) monomer LAl (NAr)]2, Ar = 2,6-iPr2C6H3) and organic azides are reported

Hongping Zhu; Zhi Yang; Jörg Magull; Herbert W. Roesky; Hans-Georg Schmidt; Mathias Noltemeyer

2005

Key concepts

Scholarcy highlights

  • Reactions between the aluminum(I) monomer LAl(NAr)]2, Ar = 2,6-iPr2C6H3) and organic azides are reported
  • The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online
  • LAl reacted with the bulky azide RN3 in toluene in a temperature range of −50 to 25 °C, resulting in the compound LAl, Ph3Si) instead of the expected AlN multiple bond species, while the reaction with tBuSi(N3)3 gave LAl(N3)N2NAl(N3)L
  • The corresponding X-ray structural analysis exhibits the Al−H and N−H bonds that are nearly arranged in position trans to the Al−NNHAr bond
  • Such files may be downloaded by article for research use

Need more features? Save interactive summary cards to your Scholarcy Library.