Hydrovinylation of Norbornene. Ligand-Dependent Selectivity and Asymmetric Variations

Norbornene undergoes Ni-catalyzed hydrovinylation, giving either a 1:1 or a 2:1 adduct depending on the size of the phosphine

Ramaiah Kumareswaran; Malay Nandi; T. V. RajanBabu

2003

Key concepts

Scholarcy highlights

  • Norbornene undergoes Ni-catalyzed hydrovinylation, giving either a 1:1 or a 2:1 adduct depending on the size of the phosphine
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  • Use of binaphthol-derived phosphoramidite ligand results in up to 80% ee for the 1:1 adduct
  • The course of the reaction is highly dependent on the ligand and the counteranion present."}" class="meta-data"/>
  • Journal of the American Chemical Society2006,128 , 54-55

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