Electrochemistry and Electrogenerated Chemiluminescence of CdTe Nanoparticles

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Yoonjung Bae; Noseung Myung; Allen J. Bard

2004

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  • Differential pulse voltammetry of TOPO-capped CdTe nanoparticles in dichloromethane and a mixture of benzene and acetonitrile showed two anodic and one cathodic peaks of the NPs themselves and an additional anodic peak resulting from the oxidation of reduced NPs
  • The fact that the Electrogenerated chemiluminescence peak occurs at about the same wavelength as the band-edge photoluminescence peak indicates that, in contrast to CdSe NPs, the CdTe NPs as synthesized had no deep surface traps that can cause a substantially red shifted ECL

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