A Thermodynamic Polymer Cross-Linking System Based on Radically Exchangeable Covalent Bonds

Schemes representing the synthesis of label compounds 1−6 as well as figures showing the controlled atom transfer radical copolymerization of MMA and 5

Yuji Higaki

2006

Key concepts

Scholarcy highlights

  • Schemes representing the synthesis of label compounds 1−6 as well as figures showing the controlled atom transfer radical copolymerization of MMA and 5
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  • By heating the poly(methacrylic ester)s containing alkoxyamine units on the side chain, the cross-linking reaction was achieved as a result of a radical exchange reaction of alkoxyamine moieties
  • It was found that the cross-linked points thermally dissociate and that the reaction system is reversible under stoichiometric control
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