Rare-Earth Silylamide-Catalyzed Selective Dimerization of Terminal Alkynes and Subsequent Hydrophosphination in One Pot

Rare-earth silylamides, Ln 3, catalyzed regio- and stereoselective dimerization of terminal alkynes in the presence of amine additives to give conjugated enynes in high yields

Kimihiro Komeyama; Tomonori Kawabata; Katsuomi Takehira; Ken Takaki

2005

Key concepts

Scholarcy highlights

  • Rare-earth silylamides, Ln3, catalyzed regio- and stereoselective dimerization of terminal alkynes in the presence of amine additives to give conjugated enynes in high yields
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