Highly Enantioselective Nickel-Catalyzed Hydrovinylation with Chiral Phosphoramidite Ligands

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Giancarlo FranciĆ²

2002

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  • Available chiral phosphoramidites are a promising class of ligands for nickel-catalyzed asymmetric hydrovinylation of vinyl arenes
  • Choosing the proper stereochemistry in each part of the modular ligand system leads to high chemoselectivities and excellent enantioselectivities up to 94%
  • Journal of the American Chemical Society2006,128 , 54-55

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