Asymmetric Total Synthesis ofent-(−)-Roseophilin: Assignment of Absolute Configuration

In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed

Dale L. Boger

2002

Scholarcy highlights

  • In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed
  • The approach enlists a room temperature heterocyclic azadiene inverse electron demand Diels−Alder reaction of dimethyl 1,2,4,5-tetrazine-3,6-dicarboxylate with the optically active enol ether 6 bearing the C23 chiral center followed by a reductive ring contraction reaction for formation of an appropriately functionalized pyrrole ring in a key 1,2,4,5-tetrazine → 1,2-diazine → pyrrole reaction sequence
  • Electronic Supporting Information files are available without a subscription to ACS Web Editions
  • Files available from the ACS website may be downloaded for personal use only
  • Information about how to use the RightsLink permission system can be found at http://pubs.acs.org/page/copyright/permissions.html
  • Journal of the American Chemical Society2014,136 , 11483-11493

Need more features? Save interactive summary cards to your Scholarcy Library.