A Series of Pincer-Ligated Rhodium Complexes as Catalysts for the Dimerization of Terminal Alkynes

A series of pincer complexes of Rh has been prepared and tested as catalysts for the dimerization of terminal alkynes

Christopher J. Pell; Oleg V. Ozerov

2014

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  • A series of pincer complexes of Rh has been prepared and tested as catalysts for the dimerization of terminal alkynes
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  • All surveyed Rh complexes acted as catalysts for dimerization of 4-ethynyltoluene, 1-hexyne, or trimethysilylacetylene
  • The products were a mixture of E- and gem-enyne isomers, with small amounts of oligomers in some cases
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  • Journal of the American Chemical Society2018,140 , 2179-2185

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