Generation and reactivity ofN,N-dimethylaminobenzotriazolylcarbene a new nucleophilic carbene

It was found that this novel carbene reacted with trans‐dibenzoylethylene in a cycloaddition, generating 2‐dimethylamino‐3‐benzoyl‐5‐phenylfuran and 2‐phenyl‐3‐ ‐4‐benzoylfuran whose structures were confirmed by 1H‐13C long range correlations as well as the structure of furan 14 being confirmed by X‐ray crystallography

Alan R. Katritzky

2009

Scholarcy highlights

  • It was found that this novel carbene reacted with trans‐dibenzoylethylene in a cycloaddition, generating 2‐dimethylamino‐3‐benzoyl‐5‐phenylfuran and 2‐phenyl‐3‐‐4‐benzoylfuran whose structures were confirmed by 1H‐13C long range correlations as well as the structure of furan 14 being confirmed by X‐ray crystallography
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