IPr3 Si3 Cl5 + : A Highly Reactive Cation with Silanide Character

Quantum chemical calculations show that the HOMO is localized at the negatively charged central silicon atom of 1 and 2, and both compounds are cations they are better described as silanides, which was corroborated by NMR investigations

Fabian Uhlemann

2016

Scholarcy highlights

  • Quantum chemical calculations show that the HOMO is localized at the negatively charged central silicon atom of 1 and 2, and both compounds are cations they are better described as silanides, which was corroborated by NMR investigations
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