Mutual Cooperation in the Formal Allyl Alcohol Nucleophilic Substitution and Hydration of Alkynes for the Construction of γ-Substituted Ketones

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Kaimeng Huang

2016

Scholarcy highlights

  • As a service to our authors and readers, this journal provides supporting information supplied by the authors
  • Mutual cooperation in the formal allyl alcohol nucleophilic substitution reaction and hydration of an alkyne has been utilized in the presence of a gold catalyst to give a series of γ‐functionalized ketones with high to excellent yields
  • This reaction involved an intramolecular O−H insertion cyclization of an alkyne to form the dihydrofuran intermediate, which was followed by the nucleophilic addition ring‐opening of a dihydrofuran to give the target compound
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