Manganese‐Catalyzed ortho‐ Alkenylation of Aromatic Amidines with Alkynes via C−H Activation

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Teng Jia; Congyang Wang

2019

Scholarcy highlights

  • As a service to our authors and readers, this journal provides supporting information supplied by the authors
  • Tolerant and efficient: The first ortho-C−H alkenylation of aromatic amidines and alkynes was enabled by earth-abundant manganese catalysis with a catalytic amount of PhMgBr
  • The first ortho-alkenylation of aromatic amidines with alkynes was realized by earth-abundant manganese catalysis through C−H activation
  • A catalytic amount of PhMgBr was found essential for improved efficiency of this transformation
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