Manganese-Catalyzed Synthesis ofcis-β-Amino Acid Esters through Organometallic CH Activation of Ketimines

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Weiping Liu; Daniel Zell; Michael John; Lutz Ackermann

2015

Scholarcy highlights

  • As a service to our authors and readers, this journal provides supporting information supplied by the authors
  • An operationally simple manganese-catalyzed CH functionalization of ketimines provides access to β-amino acid esters. The mechanism of this transformation was studied, and its utility proven by further modifications of the synthetically useful β-amino acid esters into attractive compounds
  • Manganese-catalyzed CH functionalization reactions of ketimines set the stage for the expedient synthesis of cis-β-amino acid esters through site- and regioselective alkene annulations
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