Silver(I)‐ and Base‐Mediated formal [4+3] Cycloaddition of in Situ generated 1,2‐Diaza‐1,3‐dienes with C,N ‐Cyclic Azomethine Imines: An Efficient Protocol for the Synthesis of Tetrazepine Derivatives

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Zefei Li; Shuaikang Li; Tianjiao Kan; Xinyue Wang; Xin Xin; Yunlei Hou; Ping Gong

2020

Scholarcy highlights

  • As a service to our authors and readers, this journal provides supporting information supplied by the authors
  • A silver(I)- and base-mediated formal cycloaddition reaction of in situ generated 1,2-diaza-1,3-dienes with in situ formed C,N-cyclic azomethine imines has been developed. This protocol provided an efficient method for the synthesis of biologically important 1,2,4,5-tetrazepine derivatives with a wild substrate scope and excellent functional group tolerance in moderate to excellent yields
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