Elektroreduktion organischer Verbindungen, 6. ElektroreduktionN,N-disubstituierter Thioamide in Gegenwart von Elektrophilen

Electron-uptake by the N,N-disubstituted thioamides 1–4 in aprotic medium and the behaviour of their radical anions depend substantially on the nature of the thioacyl group and the nitrogen substituents as shown by polarographic and cyclovoltammetric measurements. – Good yields of the α-amino thioethers 8–13 are obtained by preparative electroreduction in the presence of alkylating agents

Jürgen Voß

2007

Scholarcy highlights

  • Electron-uptake by the N,N-disubstituted thioamides 1–4 in aprotic medium and the behaviour of their radical anions depend substantially on the nature of the thioacyl group and the nitrogen substituents as shown by polarographic and cyclovoltammetric measurements. – Good yields of the α-amino thioethers 8–13 are obtained by preparative electroreduction in the presence of alkylating agents
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