Thickness-Driven Orthorhombic to Triclinic Phase Transformation in Pentacene Thin Films

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L. F. Drummy

2005

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  • Pentacene films are thermally evaporated onto amorphous carbonā€coated mica substrates held at room temperature
  • The crystal structure and morphology of the films are analyzed using electron microscopy and diffraction, and a new orthorhombic structure is characterized for films below a critical thickness
  • Evidence that the orthorhombic structure is thermodynamically stable at low film thickness due to its low surface energy is obtained
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